21.5.1 The assignment of special requirements in column o shall
normally follow clear criteria based on the data supplied in the reporting form. Where
it is considered appropriate to deviate from such criteria, this shall be clearly
documented in such a way that it can easily be retrieved on demand.
21.5.2 The criteria for making reference to the special requirements
identified in chapters 15 and 16 are
defined below with comments where relevant.
21.5.3 Paragraphs 15.2 to 15.10 and 15.20
21.5.3.1 Paragraphs 15.2 to 15.10 and 15.20 identify specific products by
name with special carriage requirements that cannot be easily accommodated in any other
way.
21.5.4 Paragraph 15.11 – Acids
21.5.4.1 Paragraph 15.11 applies to all acids unless they:
21.5.5 Paragraph 15.12 – Toxic products
21.5.5.1 All of paragraph 15.12 is added to column o according to
the following criteria:
- Inhalation LC50/ATE ≤ 2 mg/L/4h (C3 = 3 or 4),
unless in accordance with 21.7.12; and/or
- the product is a respiratory sensitizer (D3 = Sr, see also
paragraph 21.7.4); and/or
- the product is toxic to mammals by prolonged exposure (D3 =
C, M, R, T, N, or I).
21.5.5.2 Paragraphs 15.12.3 and 15.12.4 are added to column o
according to the following criterion:
- Inhalation LC50/ATE > 2 - ≤ 10 mg/L/4h (C3 =
2), unless in accordance with 21.7.12.
21.5.5.3 Paragraph 15.12.3.2 is added to column o according to the
following criteria:
- Dermal LD50/ATE ≤ 1000 mg/kg (C2 = 2, 3, or 4);
and/or
- Oral LD50/ATE ≤ 300 mg/kg (C1 = 2, 3, or 4).
21.5.6 Paragraph 15.13 – Cargoes protected by additives
21.5.6.1 The requirement to assign paragraph 15.13 to column o is
based on the information related to the product's tendency to polymerize, decompose,
oxidize or undergo other chemical changes which may cause a hazard under normal carriage
conditions, but which would be prevented by the addition of appropriate additives.
21.5.7 Paragraph 15.14 – Cargoes with a vapour pressure greater than
atmospheric at 37.8°C
21.5.7.1 The requirement to assign paragraph 15.14 to column o is
based on the following criterion:
21.5.8 Paragraph 15.16 – Cargo contamination
21.5.8.1 Paragraph 15.16.1 is deleted.
21.5.8.2 Paragraph 15.16.2 is added to column o according to the
following criterion:
21.5.9 Paragraph 15.17 – Increased ventilation requirements
21.5.9.1 Paragraph 15.17 shall be added to column o according to the
following criteria:
-
Inhalation LC50/ATE > 0.5 - ≤ 2 mg/L/4h (C3 = 3),
unless in accordance with 21.7.12; and/or
-
Respiratory sensitizer (D3 = Sr, see also paragraph 21.7.4); and/or
-
Toxic to mammals by prolonged exposure (D3 = C, M, R, T, N, or I);
and/or
-
Highly to severely corrosive to skin (≤ 1h exposure time) (D1 = 3B
or 3C).
21.5.10 Paragraph 15.18 – Special cargo pump-room requirements
21.5.10.1 Paragraph 15.18 shall be added to column o according to the
following criterion: Inhalation LC50/ATE ≤ 0.5 mg/L/4h (C3 = 4), unless in
accordance with 21.7.12
21.5.11 Paragraph 15.19 – Overflow control
21.5.11.1 Paragraph 15.19 shall be added to column o according to the
following criteria:
- Inhalation LC50/ATE ≤ 2 mg/L/4h (C3 = 3 or 4),
unless in accordance with 21.7.12; and/or
- Dermal LD50/ATE ≤ 1000 mg/kg (C2 = 2, 3, or 4);
and/or Oral LD50/ATE ≤ 300 mg/kg (C1 = 2, 3, or 4); and/or Respiratory
sensitizer (D3 = Sr, see also paragraph 21.7.4); and/or
- Severely corrosive to skin (≤ 3 min exposure) (D1 = 3C);
and/or
- Auto-ignition temperature ≤ 200oC; and/or
- Explosive range ≥ 40% v/v in air and flashpoint < 23°C;
and/or
- Classified as Ship Type 1 on pollution grounds.
21.5.11.2 Only paragraph 15.19.6 shall apply if the product has any of the
following properties:
- Inhalation LC50/ATE > 2 mg/L/4h - ≤10 mg/L/4h
(C3 = 2), unless in accordance with 21.7.12; and/or
- Dermal LD50/ATE > 1000 mg/kg - ≤ 2000 mg/kg (C2
= 1); and/or
- Oral LD50/ATE > 300 mg/kg - ≤ 2000 mg/kg (C1 =
1); and/or
- Skin sensitizer (D3=Ss); and/or
- Highly corrosive to skin (> 3 min - ≤ 1h exposure) (D1 =
3B); and/or
- Flashpoint ≤ 60oC; and/or
- Classified as Ship Type 2 on pollution grounds; and/or
- Pollution category X or Y.
21.5.12 Paragraph 15.21 – Temperature sensors
21.5.12.1 Paragraph 15.21 is added to column o according to the heat
sensitivity of the product. This requirement is related to pumps in cargo pump-rooms
only.