4.9.1 The shell and deck plating
of the ship and all stiffeners attached thereto should be in accordance
with Recognized Standards, unless the calculated temperature of the
material in the design condition is below -5°C due to the effect
of the low temperature cargo, in which case the material should be
in accordance with table 6.5 assuming the ambient sea and air temperature
of 0°C and 5°C respectively. In the design condition, the
complete or partial secondary barrier should be assumed to be at the
cargo temperature at atmospheric pressure and for tanks without secondary
barriers, the primary barrier should be assumed to be at the cargo
temperature.
4.9.2 Hull material forming
the secondary barrier should be in accordance with table 6.2. Metallic materials used in secondary
barriers not forming part of the hull structure should be in accordance
with Table 6.2 or 6.3 as applicable. Insulation materials forming a secondary
barrier should comply with the requirements of 4.9.7. Where the secondary barrier is
formed by the deck or side shell plating, the material grade required
by Table 6.2 should be carried into
the adjacent deck or side shell plating, where applicable, to a suitable
extent.
4.9.3 Materials used in the
construction of cargo tanks should be in accordance with Table 6.1, 6.2 or 6.3.
4.9.4 Materials other than
those referred to in 4.9.1, 4.9.2 and 4.9.3 used
in the construction of the ship which are subject to reduced temperature
due to the cargo and which do not form part of the secondary barrier
should be in accordance with table 6.5 for temperatures as determined
by 4.8. This includes inner bottom
plating, longitudinal bulkhead plating, transverse bulkhead plating,
floors, webs, stringers and all attached stiffening members.
4.9.5 The insulation materials
should be suitable for loads which may be imposed on them by the adjacent
structure.
4.9.6 Where applicable, due
to location or environmental conditions, insulation materials should
have suitable properties of resistance to fire and flame spread and
should be adequately protected against penetration of water vapour
and mechanical damage.
4.9.7.1 Materials used for
thermal insulation should be tested for the following properties as
applicable, to ensure that they are adequate for the intended service:
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.1 compatibility with the cargo
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.2 solubility in the cargo
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.3 absorption of the cargo
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.4 shrinkage
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.5 ageing
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.6 closed cell content
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.7 density
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.8 mechanical properties
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.9 thermal expansion
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.10 abrasion
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.11 cohesion
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.12 thermal conductivity
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.13 resistance to vibrations
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.14 resistance to fire and flame spread.
4.9.7.2 In addition to meeting
the above requirements, insulation materials which form part of the
cargo containment as defined in 4.2.5 should
be tested for the following properties after simulation of ageing
and thermal cycling to ensure that they are adequate for the intended
service:
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.1 bonding (adhesive and cohesive strength)
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.2 resistance to cargo pressure
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.3 fatigue and crack propagation properties
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.4 compatibility with cargo constituents and any
other agent expected to be in contact with the insulation in normal service
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.5 where applicable the influence of presence of
water and water pressure on the insulation properties should be taken into
account
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.6 gas de-absorbing.
4.9.7.3 The above properties,
where applicable, should be tested for the range between the expected
maximum temperature in service and 5°C below the minimum design
temperature, but not lower than -196°C.
4.9.8 The procedure for fabrication,
storage, handling, erection, quality control and control against harmful
exposure to sunlight of insulation materials should be to the satisfaction
of the Administration.
4.9.9 Where powder or granulated
insulation is used, the arrangements should be such as to prevent
compacting of the material due to vibrations. The design should incorporate
means to ensure that the material remains sufficiently buoyant to
maintain the required thermal conductivity and also prevent any undue
increase of pressure on the cargo containment system.