2 Air quality measurements
Clasification Society 2024 - Version 9.40
Statutory Documents - IMO Publications and Documents - Circulars - Maritime Safety Committee - MSC/Circular.729 – Design Guidelines and Operational Recommendations for Ventilation Systems in Ro-Ro Cargo Spaces – (Adopted on 4 July 1996) - Part 2 - Operational Recommendations for Minimizing Air Pollution in Ro-Ro Cargo Spaces - Appendix 3 - Recommendations for the evaluation of air quality in ro-ro cargo spaces - 2 Air quality measurements

2 Air quality measurements

 Air quality measurements should be representative of all exposed persons.

Pollutants

The concentrations of the following pollutants should be determined, nitric oxide (NO), nitrogen dioxide (NO2), carbon monoxide (CO). In addition concentrations of benzene, toluene, xylene and suspended particulate matter (SPM) should also be determined whenever possible.

There are two general approaches to air quality sampling that can be adopted. Static site monitoring, typically involving continuous monitoring techniques and personal sampling which employs both passive and active methods. Static site monitoring usually includes the more accurate and sensitive techniques, but as the sampling site is fixed the measurements are not entirely representative of exposure. Personal samplers are worn by a representative sub-set of exposed individuals throughout the sampling period. Personal sampling techniques are not usually as sensitive or accurate. Ideally, personal sampling methods should be validated using more sophisticated techniques at regular intervals.

The following methods are recommended.

Static site monitoring
Pollutant Sampling and analysis method
Nitrogen dioxide Chemiluminescence, reagent tube, grab sampling/laboratory analysis
Nitric oxide Chemiluminescence reagent tube, grab sampling/laboratory analysis
Carbon monoxide Non-dispersive infra red absorption, reagent tube, grab sampling/laboratory analysis
Benzene Real time gas chromatography
Toluene Real time gas chromatography
Xylene Real time gas chromatography
Suspended particulates* Dual beam radiation absorption, Tapered Element Oscillating Microbalance, gravimetric
*Suspended particulate matter can be sampled as total suspended particulate matter, PM10, respirable dust (≤5μm).
Personal monitoring
Pollutant Sampling and analysis method
Nitrogen dioxide Passive (badge) sampler-ion chromatography
Nitric oxide Electrochemical*
Carbon monoxide Electrochemical*
Benzene Passive badge sampler-gas chromatography/FID (Flame Ionisation Detection)
Toluene Passive badge sampler-gas chromatography/ FID
Xylene Passive badge sampler-gas chromatography/ FID
Suspended particulates** Personal sampler, gravimetric
* Electrochemical methods are susceptible to interference, therefore it is recommended that these methods are regularly validated by intercomparison with other techniques in the test environment.
** Suspended particulate matter can be sampled as total suspended particulate matter or respirable dust (≤5μm).

 Supplementary measurements of local air velocity, temperature and relative humidity should also be undertaken.


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