1.1 Definition of exposure limits and flammability limit
An exposure limit value means the highest acceptable average
concentration (time-weighted mean value) of a substance or, in some cases, of a mixture
of substances in the air breathed by the occupants. The concentrations are usually given
in parts per million (ppm) or mg/m3. An exposure limit value refers either to
a long-term exposure level or a maximum limit value. Short-term exposure level is also
used.
Long-term exposure level, means the exposure limit value for exposure during the
entire working day (normally 8 hours).
Maximum exposure level means the highest concentration reached.
A short-term exposure level means the time-weighted mean exposure value over a
short period of 10 or 15 minutes, dependent on the national occupational exposure
standards.
Lower Explosion Limit (LEL) means concentration of flammable gas, vapour or mist
in air below which an explosive gas atmosphere will not be formed. Also known as Lower
flammability limit.
1.2 Pollutants of interest
The exhaust gases generated by internal combustion engines contain hundreds of chemical
substances. The main part of them are nitrogen (N2), carbon dioxide
(CO2), oxygen (O2), carbon monoxide (CO), nitric oxide (NO),
nitrogen dioxide (NO2) aldehydes such as formaldehyde, polyaromatic
hydrocarbons such as benzo(a)pyrene and organic and particulate bound lead.
Among the pollutants emitted in the exhaust gases of petrol and diesel engines, CO is
generally of the most significant concern for petrol engines and NOx for
diesel engines. Lead, particulate matter (PM) and benzo(a)pyrene are also of a
significant concern.
Knowledge of the effects of other pollutants to the health is at present insufficient.
However, considerable research is being undertaken.
Monitoring of occupational hygiene should be planned and its results should be assessed
by a qualified expert, with special training in this field. The studies should be
carried out in cooperation with the monitoring staff, the management of the ship
concerned and the relevant Administrations.
1.3 Rate of air change
Regulations II-2/19.3.4 and 20.3 of the 1974 SOLAS Convention, as amended, provides requirements for
rate of air changes which are intended to limit maximum concentration of pollutants
during loading and unloading and also to prevent a build-up of hazardous and flammable
gases in the ro-ro cargo spaces when the ship is at sea with a cargo of motor vehicles.
These regulations provide the minimum acceptable standards for ventilation.