Emergency Schedules for SPILLAGE
SPILLAGE SCHEDULE Alfa
S–A
TOXIC SUBSTANCES
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid contact, even when wearing protective clothing.
Stop leak if practicable.
Contaminated
clothing should be washed off with water and then
removed.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash
overboard with copious quantities of water. Do not direct water jet
straight onto the spillage. Keep clear of effluent. Clean the area
thoroughly.
|
| Cargo transport units (large spillage)
|
Keep
bridge and living quarters upwind.
Wash overboard with copious
quantities of water. Do not direct water jet straight onto the
spillage. Keep clear of effluent. Clean the area
thoroughly.
|
| Spillage under deck
|
Packages
(small spillage)
|
Do
not enter space without self-contained breathing apparatus. Check
atmosphere before entering (toxicity and explosion hazard). If
atmosphere cannot be checked, do not enter. Let vapours evaporate.
Keep clear.
Liquids: Provide good ventilation of the space. Restrict
flow of liquid to an enclosed area (e.g. by barricading with
inert material or cement if available).
Solids: Collect spillage. Dispose of overboard.
Otherwise, keep clear. Radio for expert
ADVICE.
|
| Cargo
transport units (large spillage)
|
Keep
clear. Radio for expert ADVICE. After hazard evaluation by experts,
you may proceed.
Provide adequate ventilation. Do not
enter space without self-contained breathing apparatus.
Check atmosphere before entering (toxicity and
explosion hazard). If atmosphere cannot be checked, do not
enter. Let vapour evaporate, keep clear. Where the ventilation
system is used, particular attention should be taken to prevent
toxic vapours or fumes entering occupied areas of the ship, e.g.
living quarters, machinery spaces, working areas.
Liquids: Provide good ventilation of the
space. Wash down to the bottom of the hold. Pump overboard.
Solids: Collect spillage. Keep spilt
solids dry and cover with plastic sheet. Dispose of overboard.
Otherwise, close hatches. Wait until the ship arrives in
port.
|
| Special cases:
|
|
| Marine pollutant mark
|
Keep
disposal overboard as low as possible. Dilute with copious
quantities of water. Report incident according to MARPOL reporting requirements.
|
| UN 3546
|
Substances might be spilled when the articles are damaged.
Undamaged articles can be collected.
|
SPILLAGE SCHEDULE Bravo
S–B
CORROSIVE SUBSTANCES
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid contact, even when wearing protective clothing.
Keep clear of effluent. Keep clear of evolving vapours.
Even short-time inhalation of small quantities of
vapour can cause breathing difficulties.
Use
of water on the substance may cause a violent reaction and
produce toxic vapours. Substance may damage ship's construction
materials.
Contaminated clothing should be
washed off with water and then removed.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash
overboard with copious quantities of water. Do not direct water jet
straight onto the spillage. Keep clear of effluent. Clean the area
thoroughly.
|
| Cargo transport units (large spillage)
|
Keep
bridge and living quarters upwind. Protect crew and living quarters
against corrosive or toxic vapours by using water spray to drive
vapours away.
Wash overboard with copious quantities of water. Do
not direct water jet straight onto the spillage. Keep clear of
effluent. Clean the area thoroughly.
|
| Spillage under deck
|
Packages
(small spillage)
|
Provide adequate ventilation. Do not enter space without
self-contained breathing apparatus. Check atmosphere before entering
(toxicity and explosion hazard). If atmosphere cannot be checked, do
not enter. Let vapour evaporate. Keep clear.
Liquids: Provide good ventilation of the space. Wash
down to the bottom of the hold. Use copious quantities of water.
Pump overboard.
Solids: Collect
spillage. Dispose of overboard. Wash residues down to the bottom
of the hold. Use copious quantities of water. Pump
overboard.
|
| Cargo
transport units (large spillage)
|
Keep
bridge and living quarters upwind. Protect crew and living quarters
against corrosive or toxic vapours by using water spray to drive
vapours away.
Do not enter space. Keep clear. Radio
for expert ADVICE. After hazard evaluation by experts, you may
proceed.
Provide adequate ventilation. Do not
enter space without self-contained breathing apparatus. Check
atmosphere before entering (toxicity and explosion hazard). If
atmosphere cannot be checked, do not enter. Let vapours
evaporate, keep clear. Where a ventilation system is used,
particular attention should be taken in order to prevent toxic
vapours or fumes entering occupied areas of the ship, e.g.
living quarters, machinery spaces, working areas.
Liquids: Provide good ventilation of the
space. Wash down to the bottom of the hold. Use copious
quantities of water. Pump overboard.
Solids: Collect spillage. Dispose of overboard. Wash
residues down to the bottom of the hold. Use copious quantities
of water. Pump overboard.
|
| Special cases:
|
|
| Marine pollutant mark
|
Report incident according to MARPOL reporting requirements.
|
| UN 2802, UN 2809, UN 3506
|
No
reaction with water. Not highly corrosive to protective clothing.
Collect spillages if practicable. Try to avoid disposal overboard.
Radio for expert ADVICE.
|
| UN 3547
|
Substances might be spilled when the articles are damaged.
Undamaged articles can be collected.
|
SPILLAGE SCHEDULE Charlie
S–C
FLAMMABLE, CORROSIVE LIQUIDS
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid contact, even when wearing protective clothing.
Keep clear of effluent. Keep clear of evolving
vapours.
Even short-time inhalation of small
quantities of vapour can cause breathing difficulties. Use of
water on the substance may cause violent reaction and produce
toxic vapours. Substance may damage the ship's construction
materials.
Spillage or reaction with water
may evolve flammable vapours. Avoid all sources of ignition
(e.g. naked lights, unprotected light bulbs, electric handtools,
friction).
Contaminated clothing must be
washed off with water and then removed.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash
overboard with copious quantities of water. Do not direct water jets
straight onto the spillage. Keep clear of effluent. Clean the area
thoroughly.
|
| Cargo transport units (large spillage)
|
Keep
bridge and living quarters upwind. Protect crew and living quarters
against corrosive or toxic vapours by using water spray to drive
vapours away.
Wash overboard with copious quantities of water. Do
not direct water jets straight onto the spillage. Keep clear of
effluent. Clean the area thoroughly.
|
| Spillage under deck
|
Packages
(small spillage)
|
Provide adequate ventilation. Do not enter deck without
self-contained breathing apparatus. Check atmosphere before entering
(toxicity and explosion hazard). If atmosphere cannot be checked, do
not enter. Let vapours evaporate, keep clear.
Liquids: Provide good ventilation of the space. Use
water spray on effluent in hold to avoid ignition of flammable
vapours. Wash down to the bottom of the hold. Use copious
quantities of water. Pump overboard.
Solids: Collect spillage. Dispose of overboard. Wash
residues down to the bottom of the hold. Use copious quantities
of water. Pump overboard.
|
| Cargo
transport units (large spillage)
|
Keep
bridge and living quarters upwind. Protect crew and living quarters
against corrosive or toxic vapours by using water spray to drive
vapours away.
Do not enter space. Keep clear. Radio
for expert ADVICE. After hazard evaluation by experts, you may
proceed.
Provide adequate ventilation. Do
not enter space without self-contained breathing apparatus.
Check atmosphere before entering (toxicity and explosion
hazard). If atmosphere cannot be checked, do not enter. Let
vapours evaporate, keep clear. Where a ventilation system is
used, particular attention should be taken in order to prevent
toxic vapours or fumes entering occupied areas of the ship, e.g.
living quarters, machinery spaces, working areas.
Liquids: Provide good ventilation of the
space. Use water spray on effluent to avoid ignition of
flammable vapours. Wash down to the bottom of the hold. Use
copious quantities of water. Pump overboard.
Solids: Collect spillage. Dispose of overboard. Wash
residues down to the bottom of the hold. Use copious quantities
of water. Pump overboard.
|
| Special cases:
|
|
| Marine pollutant mark
UN 2029, UN
3484
|
Report incident according to MARPOL reporting requirements.
Self-ignition of spilt material is possible.
|
SPILLAGE SCHEDULE Delta
S–D
FLAMMABLE LIQUIDS
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked
lights, unprotected light bulbs, electric handtools, friction).
Stop leak if practicable.
Avoid contact, even when wearing protective clothing. Spillage
may evolve flammable vapours.
Contaminated
clothing must be washed off with water and then
removed.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash
overboard with copious quantities of water. Do not direct water jet
straight onto the spillage. Keep clear of effluent. Clean the area
thoroughly.
|
| Cargo transport units (large spillage)
|
Keep
bridge and living quarters upwind.
Wash overboard with copious
quantities of water. Do not direct water jet straight onto the
spillage. Keep clear of effluent. Clean the area
thoroughly.
|
| Spillage under deck
|
Packages
(small spillage)
|
Shut
off all possible sources of ignition in the space. Provide adequate
ventilation. Do not enter space without self-contained breathing
apparatus. Check atmosphere before entering (toxicity and explosion
hazard). If the atmosphere cannot be checked, do not enter. Let
vapours evaporate, keep clear.
Provide good ventilation of the
space. Use water spray on effluent in hold to avoid ignition of
flammable vapours. Wash down to the bottom of the hold. Pump
overboard.
|
| Cargo
transport units (large spillage)
|
Keep
bridge and living quarters upwind. Protect crew and living quarters
against corrosive or toxic vapours by using water spray to drive
vapours away.
Do not enter space. Keep clear. Radio for expert
ADVICE. After hazard evaluation by experts, you may proceed.
Provide adequate ventilation. Do not enter space without
self-contained breathing apparatus. Check atmosphere before
entering (toxicity and explosion hazard). If atmosphere cannot
be checked, do not enter. Let vapour evaporate, keep clear.
Where a ventilation system is used, particular attention should
be taken in order to prevent toxic vapours or fumes entering
occupied areas of the vessel, e.g. living quarters, machinery
spaces, working areas.
Provide good ventilation of the
space. Use water spray on effluent in the space to avoid
ignition of flammable vapours. Wash down to the bottom of the
hold. Use copious quantities of water. Pump
overboard.
|
| Special cases:
|
|
| Marine pollutant mark
UN 2749
|
Report incident according to MARPOL reporting requirements.
Self-ignition of spilt material is possible.
|
| UN 3359
|
This
is a cargo transport unit under fumigation. When opened, it will be
ventilated. However, experience has shown that toxic fumigants will
stay within packaging material and in non-ventilated areas. Obtain
information about the fumigation agent.
|
| UN 3540
|
Substances might be spilled when the articles are damaged.
Undamaged articles can be collected and repacked.
|
SPILLAGE SCHEDULE Echo
S–E
FLAMMABLE LIQUIDS, FLOATING ON WATER
| General comments
|
Avoid sources of ignition (e.g. naked lights, unprotected light
bulbs, electric handtools). Liquid is flammable and spillage may
evolve flammable vapours.
Wear suitable protective
clothing and self-contained breathing apparatus. Stop leak if
practicable.
In general, substances covered
under this schedule will have fuel-oil-like properties. They are
immiscible with water and are liable to float on the surface of
water. The use of inert absorbent material, as used in machinery
spaces, is appropriate in all cases. For sticky liquids, shovels
may be used, preferably shovels made of non-sparking or
non-ferrous material.
You may use light oil
or soap-like products (surfactants) to clean small areas. Clean
the area thoroughly because of the flammability hazard.
Any pumping of spilled liquid overboard will create
an oil spill on the sea surface. In this case, contact coastal
authorities.
Report discharge overboard
according to MARPOL reporting
requirements.
|
| Spillage on deck
|
Packages
(small spillage)
|
Collect spillage in oil drums, metal boxes or salvage packagings.
You may use inert absorbent material.
|
| Cargo transport units (large spillage)
|
Restrict flow of leakage to an enclosed area (e.g. by diking with
inert material or cement).
Collect spillage in oil drums, metal
boxes or salvage packagings. You may use inert absorbent
material.
Otherwise, wash overboard with copious
quantities of water.
|
| Spillage under deck
|
Packages
(small spillage)
|
Shut
off possible sources of ignition in the space. Provide adequate
ventilation. Do not enter space without self-contained breathing
apparatus. Check atmosphere before entering (toxicity and explosion
hazard). If atmosphere cannot be checked, do not enter. Let vapours
evaporate.
Collect spillage in oil drums, metal boxes or salvage
packagings. You may use inert absorbent material. Keep collected
spillages in well ventilated areas or on deck only.
|
| Cargo
transport units (large spillage)
|
Shut
off possible sources of ignition in the space. Provide adequate
ventilation. Do not enter deck without self-contained breathing
apparatus. Check atmosphere before entering (toxicity and explosion
hazard). If atmosphere cannot be checked, do not enter. Let vapours
evaporate. Where a ventilation system is used, particular attention
should be taken in order to prevent toxic vapours or fumes entering
occupied areas of the ship, e.g. living quarters, machinery spaces,
working areas.
Provide good ventilation of the space. Use water
spray on effluent in the space to avoid ignition of flammable
vapours. Wash down to the bottom of the hold. Use copious
quantities of water.
Treat effluent according to
Shipboard Oil Pollution Emergency Plan. Otherwise, radio for
expert ADVICE.
|
| Special cases:
|
|
| UN 1136, UN 1993
|
These substances may be miscible with water and hence not float on
the surface. In this case, SPILLAGE SCHEDULE S–D will be
appropriate.
|
| UN 1139, UN 1263, UN 1866
|
No
thorough cleaning of spillage site necessary. Residues will dry out
and coat surfaces.
|
SPILLAGE SCHEDULE Foxtrot
S–F
WATER-SOLUBLE MARINE POLLUTANTS
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Stop leak if practicable.
Substances covered under
this schedule will present a hazard to the marine environment.
Try to avoid disposal overboard.
The use of
inert absorbent material, as used in machinery spaces, is
appropriate in all cases. For sticky liquids, shovels may be
used.
Discharge of spilled substance
overboard will damage the marine environment, including living
resources of the sea. In this case, contact coastal authorities.
Report discharge overboard according to MARPOL reporting
requirements.
|
| Spillage on deck
|
Packages
(small spillage)
|
Liquids: Smother spillage with inert absorbent material.
Collect spillage in oil drums, metal boxes or
salvage packagings.
Solids: Collect
material.
|
| Cargo transport units (large spillage)
|
Restrict flow of leakage to an enclosed area (e.g. by barricading
with inert material or cement if available).
Liquids: Collect spillage in empty tanks, oil drums,
metal boxes or salvage packagings. You may use inert absorbent
material.
Solids: Collect spillage in
oil drums or metal boxes.
|
| Spillage under deck
|
Packages
(small spillage)
|
Liquids: Smother spillage with inert absorbent material.
Collect spillage in oil drums, metal boxes or
salvage packagings.
Solids: Collect
material.
|
| Cargo
transport units (large spillage)
|
Restrict flow of leakage to an enclosed area (e.g. by barricading
with inert material or cement if available).
Liquids: Collect spillage in empty tanks, oil drums,
metal boxes or salvage packagings. You may use inert absorbent
material.
Solids: Collect spillage in
oil drums or metal boxes. Otherwise, wash down to the bottom of
the hold. Use copious quantities of water. Treat effluent
according to Shipboard Oil Pollution Emergency Plan.
|
| Special cases: None.
|
SPILLAGE SCHEDULE Golf
S–G
FLAMMABLE SOLIDS AND SELF-REACTIVE SUBSTANCES
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked lights,
unprotected light bulbs, electric handtools, friction). Wear
non-sparking footwear.
Stop leak if
practicable.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash overboard with copious quantities of water. Keep
clear of effluent.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Do
not enter space without self-contained breathing apparatus.
Check atmosphere before entering (toxicity and
explosion hazard). Collect and contain spillage if practicable.
Dispose of overboard.
Collect spillage using
soft brushes and plastic trays.
|
| Cargo
transport units (large spillage)
|
Provide adequate ventilation.
Do not enter space
without self-contained breathing apparatus.
Check atmosphere before entering (toxicity and explosion
hazard). Collect and contain spillage if practicable. Dispose of
overboard. Collect spillage using soft brushes and plastic
trays.
|
| Special cases:
|
|
| UN 3541
|
Substances might be spilled when the articles are damaged.
Undamaged articles can be collected.
|
SPILLAGE SCHEDULE Hotel
S–H
FLAMMABLE SOLIDS (MOLTEN MATERIAL)
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked lights,
unprotected light bulbs, electric handtools, friction). Wear
non-sparking footwear.
Stop leak if
practicable.
Do not touch or walk on spilled
material.
|
| Spillage on deck
|
Packages
(small spillage)
|
Smother with dry inert material. Dispose of overboard.
|
| Cargo transport units (large spillage)
|
|
| Spillage under deck
|
Packages
(small spillage)
|
|
| Cargo
transport units (large spillage)
|
|
| Special cases: None.
|
|
SPILLAGE SCHEDULE India
S–I
FLAMMABLE SOLIDS (REPACKING POSSIBLE)
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked lights,
unprotected light bulbs, electric handtools, friction). Wear
non-sparking footwear.
Stop leak if
practicable.
|
| Spillage on deck
|
Packages
(small spillage)
|
Collect spillage and repack if practicable.
Otherwise, wash overboard with copious quantities of water.
Keep clear of effluent.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Collect spillage and repack if practicable.
|
| Cargo
transport units (large spillage)
|
| Special cases: None.
|
|
SPILLAGE SCHEDULE Juliet
S–J
WETTED EXPLOSIVES AND CERTAIN SELF-HEATING SUBSTANCES
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked
lights, unprotected light bulbs, electric handtools, friction).
Wear non-sparking footwear.
Stop leak if
practicable.
Dried out material may explode
if exposed to heat, flame, friction, or shock.
|
| Spillage on deck
|
Packages
(small spillage)
|
Keep spillage wet.
Dispose of solid material
overboard.
Wash overboard with copious quantities of
water. Keep clear of effluent.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Keep spillage wet.
Collect and contain
spillage if practicable. Dispose of overboard. Collect spillage
using soft brushes and plastic trays.
|
| Cargo
transport units (large spillage)
|
| Special cases:
|
|
| UN 3542
|
Substances might be spilled when the articles are damaged.
Undamaged articles can be collected.
|
SPILLAGE SCHEDULE Kilo
S–K
TEMPERATURE-CONTROLLED SELF-REACTIVE SUBSTANCES
| General comments
|
If
smoke is observed, see FIRE SCHEDULE F-F.
Check
temperature reading if possible. If temperature is increasing:
see FIRE SCHEDULE F-F.
Wear suitable
protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked
lights, unprotected light bulbs, electric handtools, friction).
Wear non-sparking footwear.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash
overboard with copious quantities of water. Keep clear of
effluent.
|
| Cargo transport units (large spillage)
|
Wash
overboard with copious quantities of water. Keep clear of effluent.
Leave units closed.
|
| Spillage under deck
|
Packages
(small spillage)
|
Not applicable. According to the IMDG Code, under deck
stowage not allowed. Radio for expert ADVICE.
|
| Cargo
transport units (large spillage)
|
| Special cases:
|
|
SPILLAGE SCHEDULE Lima
S–L
SPONTANEOUSLY COMBUSTIBLE, WATER-REACTIVE SUBSTANCES
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked lights,
unprotected light bulbs, electric handtools, friction). Wear
non-sparking footwear.
DO NOT USE
WATER.
|
| Spillage on deck
|
Packages
(small spillage)
|
Avoid getting water on spilled substances or inside
cargo transport units. Smother with dry inert material. Dispose of
overboard immediately.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Not applicable. According to the IMDG Code, under deck
stowage not allowed. Radio for expert ADVICE.
|
| Cargo
transport units (large spillage)
|
| Special cases:
|
|
| UN 2210, UN 2968
|
These
substances are allowed to be carried under deck. Take action as
given for on deck stowage.
|
SPILLAGE SCHEDULE Mike
S–M
HAZARD OF SPONTANEOUS IGNITION
| General comments
|
Substances covered by this schedule may ignite within 5 minutes
after contact with air. See firefighting guidance: FIRE SCHEDULE
F–G.
|
| Spillage on deck
|
Packages
(small spillage)
|
|
| Cargo transport units (large spillage)
|
|
| Spillage under deck
|
Packages
(small spillage)
|
|
| Cargo
transport units (large spillage)
|
|
| Special cases:
|
|
| UN 3542
|
Substances might be spilled when the articles are damaged.
Undamaged articles can be collected.
|
SPILLAGE SCHEDULE November
S–N
SUBSTANCES REACTING VIGOROUSLY WITH WATER
| General comments
|
Wear
suitable protective clothing and self-contained breathing
apparatus.
Avoid all sources of ignition (e.g.
naked lights, unprotected light bulbs, electric handtools,
friction). Wear non-sparking footwear.
Stop
leak if practicable.
|
| Spillage on deck
|
Packages
(small spillage)
|
If dry, contain and collect spillage if practicable.
Dispose of overboard.
Avoid contact with water except to wash
residues overboard with copious quantities of water. Keep clear
of effluent.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Provide adequate ventilation.
Check atmosphere
before entering space (toxicity and explosion hazards). If
atmosphere cannot be checked, do not enter. Do not enter space
without self-contained breathing apparatus.
Keep dry.
Collect spillages using soft brushes and plastic trays.
If dry, collect and contain spillage if
practicable. Dispose of overboard.
If wet, use
inert absorbent material. Do not use combustible material.
Dispose of overboard.
|
| Cargo
transport units (large spillage)
|
| Special cases:
|
|
| UN 3543
|
Substances might be spilled when the articles are
damaged.
Undamaged articles can be collected.
|
SPILLAGE SCHEDULE Oscar
S–O
SUBSTANCES DANGEROUS WHEN WET (NON-COLLECTABLE ARTICLES)
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked lights,
unprotected light bulbs, electric handtools, friction). Wear
non-sparking footwear.
Stop leak if practicable.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash overboard with copious quantities of water. Keep
clear of effluent.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Do
not enter space without self-contained breathing apparatus.
If
dry, collect and contain spillage if practicable. Keep
dry. Dispose of overboard. Avoid contact with water except to
wash residues with copious quantities of water. Keep clear of
effluent.
If wet, wash down to the bottom of the
hold. Use copious quantities of water. Pump overboard. If gas is
developing, provide good ventilation of the hold. Use water
spray on effluent in hold to avoid ignition of flammable
vapours.
|
| Cargo
transport units (large spillage)
|
Do
not enter space without self-contained breathing apparatus.
If
dry, collect and contain spillage if practicable. Keep
dry. Dispose of overboard. Avoid contact with water except to
wash residues with copious quantities of water. Keep clear of
effluent.
If wet, wash down to the bottom of the
hold. Use copious quantities of water. Pump overboard. If gas is
developing, provide good ventilation of the hold. Use water
spray on effluent in hold to avoid ignition of flammable
vapours. Where a ventilation system is used, particular
attention should be taken in order to prevent toxic vapours or
fumes entering occupied spaces of the ship, e.g. living
quarters, machinery spaces, working areas.
|
| Special cases:
|
|
| UN 1295
|
Beware of a highly flammable atmosphere.
|
SPILLAGE SCHEDULE Papa
S–P
SUBSTANCES DANGEROUS WHEN WET (COLLECTABLE ARTICLES)
| General comments
|
Wear
suitable protective clothing and self-contained breathing
apparatus.
|
| Spillage on deck
|
Packages
(small spillage)
|
Contain and collect spillage if practicable. Dispose of
overboard.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Provide adequate ventilation.
Do not
enter space without self-contained breathing apparatus. Contain
and collect spillages if practicable. Dispose of
overboard.
|
| Cargo
transport units (large spillage)
|
| Special cases:
|
|
| UN 3257, UN 3258
|
Hot
substance. No hazard when cool.
|
| UN 3316
|
If
FIRST AID KIT, collect articles and repack.
|
| UN 3363, UN 3548
|
Substances might be spilled when the articles or machinery are
damaged.
Undamaged articles can be collected.
Take care
of hazardous properties according to transport documents or
radio for expert ADVICE.
|
SPILLAGE SCHEDULE Quebec
S–Q
OXIDIZING SUBSTANCES
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked lights,
unprotected light bulbs, electric handtools, friction). Wear
non-sparking footwear.
May ignite combustible
material (e.g. wood, paper, clothing). Stop leak if
practicable.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash overboard with copious quantities of water. Keep
clear of effluent.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Do
not enter space without self-contained breathing apparatus.
If
dry, contain and collect spillage if practicable.
Dispose of overboard.
If wet, use inert absorbent
material. Do not use combustible material.
If
liquid, wash down to the bottom of the hold, using
copious quantities of water. Pump overboard.
Dispose of
overboard.
|
| Cargo
transport units (large spillage)
|
Provide adequate ventilation.
Do not enter space
without self-contained breathing apparatus.
If dry, contain and collect spillage if practicable.
Dispose of overboard.
If wet, use
inert absorbent material. Do not use combustible material.
If liquid, wash down to the bottom of
the hold, using copious quantities of water. Pump
overboard.
Dispose of overboard.
|
| Special cases:
|
|
| UN 3544
|
Substances might be spilled when the articles are damaged.
Undamaged articles can be collected.
|
SPILLAGE SCHEDULE Romeo
S–R
ORGANIC PEROXIDES
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Contact of substance (or vapour) with eyes may
cause blindness within minutes.
Avoid all
sources of ignition (e.g. naked lights, unprotected light bulbs,
electric handtools, friction). Wear non-sparking footwear.
Stop leak if practicable.
Substances covered by this schedule are liable to
explode by exposure to heat or ignition.
In
case of smoke evolution, see appropriate FIRE SCHEDULE.
Radio for expert ADVICE or contact manufacturer.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash overboard with copious quantities of water. Keep
clear of effluent. Collect damaged or leaking receptacles and
dispose of overboard.
Handle with care.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Not applicable. According to the IMDG Code, under deck
stowage not allowed. Radio for expert ADVICE.
|
| Cargo
transport units (large spillage)
|
| Special cases:
|
|
| UN 3545
|
Substances might be spilled when the articles are damaged.
Undamaged articles can be collected.
|
SPILLAGE SCHEDULE Sierra
S–S
RADIOACTIVE MATERIAL
| General comments
|
Evacuate compartment or downwind area of non-essential personnel.
Provide respiratory protection to personnel in downwind area.
For ships carrying radiation monitoring equipment,
measure radiation levels. In this case, assess the extent of
contamination and resultant radiation level of the package, the
adjacent areas and, if necessary, all other material which has
been carried in the conveyance.
Define a zone for
restricted entry. Personnel should not enter this zone without
suitable protective clothing and self-contained breathing
apparatus.
Limit entry of personnel to the restricted
zone for the shortest time possible.
Cover liquid spill
with inert absorbent materials, if available. Cover powder
spills with plastic sheet or tarpaulin to minimize spread.
If exposure of personnel is suspected, clean body and
hair with warm water and soap; discharge resultant washings
directly overboard.
Record the names of potentially
exposed persons. Ensure medical examination of these persons
after reaching any medical staff.
Emergency procedures,
if established for the ship or the specific cargo by relevant
authorities or the shipper, should be followed.
For ships
carrying radiation monitoring equipment, continue monitoring the
radiation levels. Radio for expert ADVICE.
|
| Spillage on deck
|
Packages
(small spillage)
|
Wash
spillages overboard with copious quantities of water. Keep clear of
effluent.
Packages damaged or leaking radioactive contents may be
removed to an acceptable restricted access interim location.
Isolate and sheet over. Do not remove packages from restricted
access zone until approved by the competent
authority.
|
| Cargo transport units (large spillage)
|
Let
released gas escape. Keep clear. Use water spray to protect bridge,
living quarters and personnel from precipitation of vapours (water
curtain).
Absorb liquid spillage, where practicable, using
absorbent material. Isolate and sheet over.
Packages
damaged or leaking radioactive contents may be removed to an
acceptable restricted access interim location. Isolate and sheet
over. Do not remove packages from restricted access zone until
approved by the competent authority.
Wash residues of
liquids or solids overboard with copious quantities of water
(use spray nozzles). Do not allow water to enter
receptacles.
|
| Spillage under deck
|
Packages
(small spillage)
|
Provide adequate ventilation.
Let released gas escape, keep
clear. Where a ventilation system is used, particular attention
should be taken in order to prevent radioactive vapours or fumes
entering occupied areas of the ship, e.g. living quarters,
machinery spaces, working areas.
Keep solids dry.
Absorb liquid spillage, where practicable, using inert
absorbent material. Isolate and sheet over.
Packages
damaged or leaking radioactive contents may be removed to an
acceptable restricted access interim location. Isolate and sheet
over. Do not remove packages from restricted access zone until
approved by the competent authority.
Keep working period
of emergency team in space as short as possible.
|
| Cargo
transport units (large spillage)
|
Do
not enter space. Radio for expert ADVICE.
If liquid, or vapour
is developing: Where a ventilation system is used,
particular attention should be taken in order to prevent
radioactive vapours entering occupied areas of the ship, e.g.
living quarters, machinery spaces, working areas. Use water
spray to protect bridge, living quarters and personnel from
precipitation of vapours evolving from the hold (water
curtain).
|
| Special cases:
|
|
| UN 2977, UN 2978, UN 3507
|
Avoid
contact, even when wearing protective clothing. Keep clear of
evolving vapours. Even short-time inhalation of small quantities of
vapour can cause breathing difficulties.
Bear in
mind that gases are heavier than air. Measures should be taken
to prevent leaking gases from penetrating into any other part of
the ship.
Keep bridge and living quarters
upwind. Protect crew and living quarters against corrosive and
toxic vapours by using water spray to drive vapours away.
Do not enter space without protective equipment.
Keep clear. Radio for expert ADVICE.
|
| UN 3332, UN 3333
|
If a
special form radioactive material is identified as being outside its
packaging, do not touch. Stay away and radio for expert
ADVICE.
|
| UN 2919, UN 3331
|
For
radioactive material, transported under special arrangement,
use special precautions, operational controls or emergency
procedures as specifically designated by the competent authorities
in their approval certificates and declared by the shipper in its
transport documents.
|
| Subsidiary labels class 4.2 or class
4.3
|
These
are pyrophoric substances, water will ignite the material. DO NOT
USE WATER. Radio for expert ADVICE.
|
| Restowing of packages
|
|
| UN 2977, UN 3324, UN 3325, UN 3326, UN 3327,
UN 3328, UN 3329, UN 3330, UN 3331
|
Check
package labels and transport documents to determine whether packages
contain fissile material.
Prior to any restowing of
these packages, radio for expert ADVICE.
|
SPILLAGE SCHEDULE Tango
S–T
DANGEROUS GOODS WITH BIOHAZARD
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Avoid handling leaking or damaged packages or keep handling
to a minimum.
Inform the public health, veterinary or
other competent authority if persons or the marine environment
might have been exposed. A competent authority to which actual
or suspected leakage is reported should notify the authorities
of any countries in which the goods may have been handled,
including countries of transit.
Radio for expert ADVICE.
Notify consignor/consignee.
|
| Spillage on deck
|
Packages
(small spillage)
|
Stop leak if practicable.
Collect potentially
contaminated packages or equipment. Isolate and sheet
over.
Wash spillage or residues overboard with copious
quantities of water. Keep clear of effluent.
Clean
contaminated area thoroughly using bleach-like products (like
sodium hypochlorite 1-6% solution or Javel water). Keep clear of
effluent.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Do not enter space.
|
| Cargo
transport units (large spillage)
|
| Special cases: None.
|
|
SPILLAGE SCHEDULE Uniform
S–U
GASES (FLAMMABLE, TOXIC OR CORROSIVE)
| General comments
|
Spaces and areas where leakages or spillages have occurred should
be evacuated downwind immediately.
Take care: Flames
may be invisible. Leaking gas may be extremely cold.
Measures should be taken to prevent leaking gases
from penetrating into any other part of the ship. Bear in mind
that some gases are heavier than air or may otherwise accumulate
in lower or non-ventilated parts of the ship. Ensure that there
is no smoking or any other open fire on board unless the leak
has been closed and all spaces have been ventilated. Particular
attention should be taken in order to prevent gases drifting
into occupied areas of the ship, e.g. living quarters, machinery
spaces, working areas.
Wear protective
clothing suitable for gas protection and self-contained
breathing apparatus.
Avoid all sources of
ignition (e.g. naked lights, unprotected light bulbs, electric
handtools, friction). Wear non-sparking footwear.
Even short inhalation of small quantities of gas
can cause breathing difficulties. Keep clear of evolving gases.
Avoid all skin contact.
Let spilt
liquefied gas evaporate. When in contact with cold
liquefied gases, most materials become brittle and are likely to
break without warning. Avoid all contact, even when wearing
protective clothing. If practicable, protect ship's
superstructure with copious quantities of water. Do not direct
water jet onto the spill.
|
| Spillage on deck
|
Packages
(small spillage)
|
Let
gas dissipate. Keep clear.
|
| Cargo transport units (large spillage)
|
Let
gas dissipate. Keep bridge and living quarters upwind.
Otherwise,
protect crew and living quarters against flammable or toxic
gases by using water spray to drive gases away (water curtain).
Spilt liquefied gas: Use water jets from as
far as practicable to accelerate evaporation, not directing them
straight onto the spill.
|
| Spillage under deck
|
Packages
(small spillage)
|
Do
not enter space. Provide adequate ventilation.
Where a
ventilation system is used, particular attention should be taken
in order to prevent gases penetrating into other areas of the
ship.
Let gas evaporate. Keep clear. Radio for expert
ADVICE.
Check atmosphere before entering (toxicity and
explosion hazard). Do not enter space without self-contained
breathing apparatus.
|
| Cargo
transport units (large spillage)
|
Do
not enter space. Provide adequate ventilation.
Where
a ventilation system is used, particular attention should be
taken in order to prevent gases drifting into other areas of the
ship.
Keep bridge and living quarters upwind.
Otherwise, protect crew and living quarters
against flammable or toxic gases by using water spray to drive
gases away (water curtain).
If practicable,
use water spray to avoid ignition of flammable gases in the
space. Radio for expert ADVICE.
Check
atmosphere before entering (toxicity and explosion hazard).
Do not enter deck without self-contained
breathing apparatus.
|
| Special cases:
|
|
| UN 1001, UN 3374
|
Heated or roughly handled receptacles may explode even after
several hours of being removed from external sources of heat. Cool
for several hours by using water.
|
| UN 1614
|
The
gas is absorbed in a porous inert material, but will evaporate if
the receptacle is damaged.
|
| UN 3501
|
A
flammable liquid, paste or powder may be expelled if the package is
ruptured. Also consult SPILLAGE SCHEDULES S-D or S-G, as
appropriate.
|
| UN 3504
|
A
flammable or toxic liquid, paste or powder may be expelled if the
package is ruptured. Also consult SPILLAGE SCHEDULES S-D, S-G or
S-A, as appropriate.
|
| UN 3505
|
A
flammable or corrosive liquid, paste or powder may be expelled if
the package is ruptured. Also consult SPILLAGE SCHEDULES S-C or S-G,
as appropriate.
|
| UN 3537, UN 3539
|
Gases
might be released when the articles are damaged.
Undamaged
articles can be collected and repacked.
|
SPILLAGE SCHEDULE Victor
S–V
GASES (NON-FLAMMABLE, NON-TOXIC)
| General comments
|
Measures should be taken to prevent leaking gases from penetrating
into any other part of the ship. Bear in mind that some gases are
heavier than air or may otherwise accumulate in lower or
non-ventilated parts of the ship. Particular attention should be
taken in order to prevent gases drifting into occupied areas of the
ship, e.g. living quarters, machinery spaces, working areas. Leaking
gas may be extremely cold.
Wear suitable protective clothing and
self-contained breathing apparatus (suffocation hazard).
Let spilt liquefied gas evaporate. When in contact
with cold liquefied gases, most materials become brittle and are
likely to break without warning. Avoid all contact, even when
wearing protective clothing. If practicable, protect ship's
superstructure with copious quantities of water. Do not direct
water jet onto the spill.
|
| Spillage on deck
|
Packages
(small spillage)
|
Let
gas dissipate. Keep clear.
|
| Cargo transport units (large spillage)
|
Let
gas dissipate.
Spilt liquefied gas: Use water
jets from as far as practicable to accelerate evaporation, not
directing them straight onto the spill.
Keep
clear of evolving gases.
|
| Spillage under deck
|
Packages
(small spillage)
|
Provide adequate ventilation.
Stop leak if practicable.
Otherwise, let gas evaporate. Keep clear.
Check
atmosphere before entering space (suffocation hazard). Do not
enter space without self-contained breathing
apparatus.
|
| Cargo
transport units (large spillage)
|
Provide adequate ventilation.
Stop leak if practicable.
Otherwise, let gas evaporate. Keep clear.
Spilt
liquefied gas: Use water jets from as far as practicable
to accelerate evaporation, not directing them straight onto the
spill.
Check atmosphere before entering space
(suffocation hazard). Do not enter space without self-contained
breathing apparatus.
|
| Special cases:
|
|
| UN 2990, UN 3072
|
No
suffocation hazard. Collect articles and repack.
|
| UN 3502
|
A
toxic liquid, paste or powder may be expelled if the package is
ruptured. Also consult SPILLAGE SCHEDULE S-A.
|
| UN 3503
|
A
corrosive liquid, paste or powder may be expelled if the package is
ruptured. Also consult SPILLAGE SCHEDULES S-C or S-G, as
appropriate.
|
| UN 3538
|
Gases
might be released when the articles are damaged.
Undamaged
articles can be collected and repacked.
|
SPILLAGE SCHEDULE Whisky
S–W
OXIDIZING GASES
| General comments
|
Areas containing leakages or spillages should be evacuated downwind
immediately. These gases may ignite combustible material and enhance
fire.
Take care: Flames may be invisible. Leaking gas
may be extremely cold.
Measures should be
taken to prevent leaking gases from penetrating into any other
part of the ship.
Ensure that there is no
smoking or any other open fire on board unless the leak has been
closed and all spaces have been ventilated. Particular attention
should be taken in order to prevent gases drifting into occupied
areas of the vessel, e.g. living quarters, machinery spaces,
working areas.
Wear suitable protective
clothing and self-contained breathing apparatus.
Avoid all sources of ignition (e.g. naked lights,
unprotected light bulbs, electric handtools, friction). Wear
non-sparking footwear.
Even short inhalation
of small quantities of gas can cause breathing difficulties.
Keep clear of evolving gases. Avoid all skin contact.
Let spilt liquefied gas evaporate. When in
contact with cold liquefied gases, most materials become brittle
and are likely to break without warning. Avoid all contact, even
when wearing protective clothing. If practicable, protect ship's
superstructure with copious quantities of water. Do not direct
water jet onto the spill.
|
| Spillage on deck
|
Packages
(small spillage)
|
Let
gas evaporate. Keep clear.
|
| Cargo transport units (large spillage)
|
Let
gas evaporate.
Keep bridge and living quarters upwind.
Otherwise, protect crew and living quarters against
flammable or toxic gases by using water spray to drive gases
away (water curtain).
Spilt liquefied gas: Use
water jets from as far as practicable to accelerate evaporation,
not directing them straight onto the spill.
|
| Spillage under deck
|
Packages
(small spillage)
|
Do
not enter space.
Provide adequate ventilation.
Where a ventilation system is used,
particular attention should be observed in order to prevent
gases penetrating into other areas of the ship.
Let gas evaporate. Keep clear. Radio for expert
ADVICE.
Check atmosphere before entering
space (toxicity and explosion hazard). Do not enter space
without self-contained breathing apparatus.
|
| Cargo
transport units (large spillage)
|
Do
not enter space.
Provide adequate ventilation.
Where a ventilation system is used,
particular attention should be observed in order to prevent
gases drifting into other areas of the ship.
Keep bridge and living quarters upwind.
Otherwise, protect crew and living quarters against gases by
using water spray to drive gases away (water curtain).
If practicable, use water spray to avoid ignition
of gases in the space. Radio for expert ADVICE.
|
| Special cases:
|
|
| UN 1072, UN 1073
|
This
is concentrated oxygen. No inhalation hazard after a short distance
from a leak. No skin irritation hazard.
|
SPILLAGE SCHEDULE X-Ray
S–X
EXPLOSIVE ITEMS AND ARTICLES
| General comments
|
Avoid all sources of ignition (e.g. naked lights, unprotected light
bulbs, electric handtools).
Electrostatic
hazard: Electric charge may ignite ammunition. Keep
spilled material away from generators of static electricity
(e.g. mobile phones, friction of synthetic polymers like PVC
gloves). Wear non-sparking footwear.
|
| Spillage on deck
|
Packages
(small spillage)
|
Articles: Sweep or pick up articles. If the
articles remain intact but appear damaged, separate out and radio
for expert ADVICE.
Spilled substance: Keep wet. Wash
spillage overboard with copious quantities of water.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Articles: Sweep or pick up articles. If the
articles remain intact but appear damaged, separate and radio for
expert ADVICE.
Spilled substance: Keep wet. Collect
spillage where practicable. Dispose of overboard.
|
| Cargo
transport units (large spillage)
|
| Special cases: None.
|
|
SPILLAGE SCHEDULE Yankee
S–Y
EXPLOSIVE CHEMICALS
| General comments
|
Avoid all sources of ignition (e.g. naked lights, unprotected light
bulbs, electric handtools). Stop leak if practicable.
Electrostatic hazard: Electric charge may ignite
ammunition. Keep spilled material away from generators of static
electricity (e.g. mobile phones, friction of synthetic polymers
like PVC gloves). Wear non-sparking footwear.
Some explosive mixtures are stabilized in such a
way that water will separate explosives from the stabilizer,
thus creating a higher risk. The explosive component becomes
very sensitive to shock and heat.
Radio for
expert ADVICE.
|
| Spillage on deck
|
Packages
(small spillage)
|
Articles: Sweep or pick up articles. If the
articles remain intact but appear damaged, separate out and ask for
expert ADVICE. Wetted articles should be jettisoned.
Spilled
substance: Keep it under water. Wash spillages overboard
with copious quantities of water.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Articles: Sweep or pick up articles. If the
articles remain intact but appear damaged, separate out and radio
for expert ADVICE. Wetted articles should be jettisoned.
Spilled substance: Keep it under water. Collect
spillages where practicable. Dispose of overboard.
|
| Cargo
transport units (large spillage)
|
| Special cases: None.
|
|
SPILLAGE SCHEDULE Zulu
S–Z
TOXIC EXPLOSIVES
| General comments
|
Wear
suitable protective clothing and self-contained breathing apparatus.
Even short inhalation of small quantities of gas
can cause breathing difficulties or lead to severe poisoning.
Avoid all sources of ignition (e.g. naked
lights, unprotected light bulbs, electric handtools).
Electrostatic hazard: Electric charge may
ignite ammunition. Keep spilled material away from generators of
static electricity (e.g. mobile phones, friction of synthetic
polymers like PVC gloves). Wear non-sparking footwear.
Particular attention should be taken in order to
prevent developing gases drifting into occupied areas of the
ship, e.g. living quarters, machinery, working areas.
Keep bridge and living quarters upwind. Otherwise,
protect crew and living quarters against gases by using water
spray to drive gases away (water curtain).
Radio for expert ADVICE.
|
| Spillage on deck
|
Packages
(small spillage)
|
Let vapours dissipate, keep clear.
Articles:
Sweep or pick up articles. If the articles remain intact but
appear damaged, separate out and ask for expert ADVICE.
Spilled substance: Keep wet. Wash spillage
overboard with copious quantities of water. Keep clear of
effluent.
|
| Cargo transport units (large spillage)
|
| Spillage under deck
|
Packages
(small spillage)
|
Do not enter space without self-contained breathing
apparatus. Check atmosphere before entering. Let vapours dissipate,
keep clear.
Articles: Sweep or pick up articles. If the
articles remain intact but appear damaged, separate out and ask
for expert ADVICE.
Spilled substance: Keep wet.
Collect spillages where practicable. Dispose of
overboard.
|
| Cargo
transport units (large spillage)
|
| Special cases: None.
|
|
|