3.4.1 The technologies available on board crude
oil tankers for the control of pressure within the cargo tank vapour
system are discussed in section 2. However, it is important to identify
the significance of pressure with respect to the evolution of hydrocarbon
vapours from a crude oil liquid phase.
3.4.2 Control of the extent of the pressure within
a crude oil cargo tank vapour system will determine the extent of
further vapour evolution from a crude oil cargo. If the pressure within
the system is controlled at the Saturated Vapour Pressure of the cargo,
then equilibrium pressure between the liquid and vapour phase is obtained
and no further VOC will evolve from the cargo. However, if the vapour
pressure in the crude oil tank vapour system is reduced to a pressure
below the Saturated Vapour Pressure of the cargo, then VOC will evolve
to restore the equilibrium balance in the system.