3.2.1 A variety of Phosphine-generating formulations
are used for in-ship in-transit or at-berth fumigations. Application
methods vary widely and include surface-only treatment, probing, perforated
tubing laid at the bottom of spaces, recirculation systems and gas-injection
systems or their combinations. Treatment times will vary considerably
depending on the temperature, depth of cargo and on the application
method used.
3.2.2 Any discharge of active packages producing
Phosphine gas represents a significant risk to the public who may
encounter them at sea. It should therefore be ensured that all waste
and residues are disposed of in an appropriate manner, either by incineration
or by disposal on shore, as recommended by the manufacturer. Clear
written instructions must be given to the master of the ship, to the
receiver of the cargo and to the authorities at the discharging port
as to how any powdery residues are to be disposed of.
3.2.3 These will vary with each formulation and
the method of application. Prior to discharge, ventilation must be
done, forced if necessary, to reduce the gaseous residues below the
occupational exposure limit values set by the flag State regulations
in the free spaces (see procedures for ventilation in 3.3.2.17 to
3.3.2.19). For safety aspects during the voyage see 3.3.2.3.