1 Theory
Clasification Society 2024 - Version 9.40
Statutory Documents - IMO Publications and Documents - Circulars - Marine Environment Protection Committee - MEPC.1/Circular.677 – Guide to Diagnosing Contaminants in Oily Bilge Water to Maintain, Operate and Troubleshoot Bilge Water Treatment Systems – (22 July 2009) - Annex – A Guide to Diagnosing Contaminants in Oily Bilge Water to Maintain, Operate and Troubleshoot Bilge Water Treatment Systems - Annex 2 – Detection of Detergents and Solvents - 1 Theory

1 Theory

 Detergents and/or some solvents and/or oils may be the cause of turbidity or cloudiness of a bilge sample. Water-soluble solvents and detergents do not emulsify in water by themselves, however, they contribute to the emulsification of oil and insoluble solvents. In many cases, water insoluble solvents act like oils in that often they form droplets (though colourless and transparent) that may be read by both 107(49) and older oil content meters. Most light scattering 107(49) OCM are more sensitive to these type of emulsions. The majority of solvents will not form stable emulsions unless emulsification enhancers are present as is the case with industrial metal cleaners and other types of formulated cleaners. Many shipboard detergents and some solvents used in the engine-room are alkaline and non-volatile and can be easily detected using a simple test described below. The presence of some solvents and detergents in the absence of oil, alone and together, form micro- and mini- emulsions in water. These contaminants, alone or together, may or may not also cause turbidity, depending on the exact composition and temperature of the processed bilge water. This type of non-oil emulsions can be detected by the OCM even when no visible turbidity exists (visible to the naked eye; visible is a relative term when instrumentation is involved).


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