1 GENERAL
1.1 The model Marine Antifoulant Model for PEC calculation for Ballast
Water (MAMPEC-BW 3.1) or latest available version may be downloaded from the website of
Deltares in the Netherlands. The website is:
https://download.deltares.nl/en/download/mampec/
1.2 Click on the
link using also the <Crtl>-button. You will be directed to the download page of
Deltares in the Netherlands. Deltares is an independent institution for applied research
in the area of water and subsoil. For the ballast water application only portable
versions are available. This means that the user is able to run the model without having
"Administrator" rights on his computer.
1.3 At the Deltares website
click on "Portable version MAMPEC 3.1.0.3 BW". Go to the right hand side of the screen
and enter your name and e-mail address. You will receive a link to download a zip-file
with the model.
1.4 Look in the directory where you downloaded the
zip-file, click on the zip-file and unpack the programme. If you follow the default
settings of the programme you will find the model with its executables in the directory
specified in the set-up conversation. You may change the standard settings to your own
choices.
1.5 Go to the specified directory and click on the
executable "mampec.exe" and the main entrance screen will be shown.
2 CALCULATION OF THE PREDICTED ENVIRONMENTAL CONCENTRATION (PEC)
2.1 This calculation procedure is important for carrying out a risk
assessment to the environment.
2.2 In order to provide a standard
approach, it is recommended that the MAMPEC-BW 3.1.0.3 or latest available version is
used to determine the PEC for each chemical identified.
2.3 When this
model is used for calculation of the predicted concentration (PEC) in the harbour,
several data have to be selected from the main menu of the programme. The entrance
screen of MAMPEC-BW 3.1.0.3 looks as follows:
NOTE: in the upper right corner of the screen a user manual is always
available.
2.4 To run the MAMPEC model three inputs are
needed:
-
.1 the Environment (first item under "model" at the left hand side of
the screen);
-
.2 the Compound (second item); and
-
.3 the Emission (third item).
2.5 Click on "Environment" and the following screen appears:
2.6 To load the GESAMP-BWWG Standard Harbour click on "Load" and the next
screen appears:
2.7 In the "Description" box you may enter a
name of the project, then click "GESAMP-BWWG Model Harbour" and successively on "Load".
You will be taken back to the "Environment" screen but now the screen is loaded with the
GESAMP-BWWG Model Harbour's specific data. It is recommended not to change the default
values if the results will have to be used for a submission to IMO with respect to an
approval in accordance with Procedure (G9).
2.8 To load the data for a compound click on "Compound", on which the
"Compound" screen appears, as follows:
2.9 Click on "Load" and a list of all the GESAMP-BWWG compounds commonly
associated with ballast water (41 compounds) will appear as follows:
2.10 For example, by clicking "Bromoform" and "Load" the data for bromoform
can be shown in the "Compound" screen, like:
2.11 In the middle of the "Compound" screen biodegradation data may be
shown for several of the 41 substances. It is advisable to start the calculation with
all rate constants set to 0 (zero) as this is considered the worst-case situation. If
the worst-case situation does not lead to the conclusion of potentially unacceptable
effects, entering available degradation data with the accompanying calculation may solve
the problem of exceeding a PEC/PNEC ratio of 1. This may be done by entering a rate
constant or a half-life in the appropriate boxes.
2.12 In addition
to the GESAMP-BWWG Harbour Environment shown above and the compound, the standard
GESAMP-BWWG emission data need to be included as part of the GESAMP-BWWG Standard model
in the same way as described already by clicking on "Emission" and successively on
"Load". The following screens appear after each other:
and
2.13 By clicking on "Default Emission GESAMP
Model Harbour" and on "Load" take you back to the emission screen, where you can
complete your input by entering the concentration of the substance under consideration
found in ballast water at the appropriate box. Successively clicking on "Calculate"
gives the final emission in g/d. NOTE, that the concentration of the substance should be
entered in mg/L (not μg/L).
2.14 All necessary input for MAMPEC
has now been defined and the model can now be run by clicking on "Run model and view
results". The following screen will appear:
2.15 In this screen some additional identifiers can be added, like a
project name. A date will automatically be added (This box is grey and cannot be
changed). It is not recommended to add information on background concentrations.
Successively press "Run model" at the right hand side of the screen. The following
screen appears:
2.16 The predicted concentrations at steady state
in the harbour and the surroundings can now easily be identified.
2.17 At the left hand side some input/output facilities are given, like the generation
of a report for publication.
2.18 The results of carrying out this
procedure for each of the chemicals associated with the BWMS will be a series of PEC
values, which should be included in a table with the Predicted No Effect Concentration
(PNEC) and the appropriate assessment factor (AF). As a first assessment, the maximum
value from the MAMPEC-BW 3.1.0.3 or latest available version calculations should be
used. If this comparison results in PEC/PNEC ratios above 1, the 95%-ile may be used. If
the PEC/PNEC ratio is still above 1, additional mitigation measures or a scientific
reasoning may be proposed for discussion in the GESAMP-BWWG.
2.19 In
addition to the mitigation measure mentioned in paragraph 2.11 above (taking into
account the degradation of the substance), it can be useful to use the concentrations in
the surroundings as a higher Tier evaluation.
2.20 The resulting
table should be reported in the main document of the submission.
3
CALCULATION OF THE PEC IN THE VICINITY OF THE SHIP (PECNEAR SHIP)
3.1 The MAMPEC-BW, latest available version, will calculate the
stationary concentration in the harbour after discharge of ballast water. To account for
local effects, near the ship at discharge, the local concentration at near ship is
estimated using the formulae suggested in Zipperle et al., 2011 (Zipperle, A., Gils J.
van, Heise S., Hattum B. van, Guidance for a harmonized Emission Scenario Document (ESD)
on Ballast Water discharge, 2011):

where
- Cmax = the maximum concentration due to near ship exposure
(μg/L) = PECnear ship
- CBW = the concentration found in the discharged ballast
water (μg/L)
- S = dilution factor based on sensitivity analysis with a higher Tier
model, default value = 5
- Cmean = the mean concentration as output from MAMPEC-BW =
called average in the MAMPEC results calculated.
3.2 The concentration calculated with this formula will be compared to
acute toxicity data for the Active Substances and Relevant Chemicals to evaluate the
short-term effects on aquatic organisms according to the ratio: