5.1 This section deals with the mixtures defined
in 3.1.2, i.e. those presenting no
safety hazard and containing at least 97% by weight of chemicals (or
"families" in the case of complex petrochemical mixtures) assessed
by IMO, which present no safety hazards. Chemicals assessed by IMO
include:
-
.1 those listed in chapters 17 and 18 of the IBC Code;
-
.2 agreed and proposed amendments to these chapters;
-
.3 hydrocarbon families, for the purpose of assessing
complex petrochemical mixtures of hydrocarbons (see annex 8).
Such a mixture may contain components with safety hazards (designated
by S or S/P in column d of the summary of minimum requirements table)
as long as they are so diluted that the final mixture presents no
safety hazard.
5.2 The pollution category and the ship type of
these mixtures are derived from those of the components by the following
calculation method. For the purpose of this calculation, unassessed
components up to 3% should be assigned to pollution category A, ship
type 2, unless they can be evaluated on the basis of GESAMP hazard
profiles, data or assimilation.
5.3 The first step is to calculate the pollution
category of the mixture by the following procedure:
-
.1 identify the pollution category of each component
from the IBC Code or the MEPC circular referred
to in 2.6;
-
.2 multiply the concentration of each identified
component in the mixture, expressed in per cent by weight, by the
factor associated with its pollution category according to the following
table 1:
Table 1
|
Pollution category
|
Factor
|
A
|
1,000
|
B
|
100
|
C
|
10
|
D
|
1
|
Appendix III
|
0
|
Diluent mineral oil
|
|
in
lube oil additives*
|
10
|
* Most lube oil additive components are produced in mineral
oil and have been assessed as produced. Sometimes more mineral oil
is added to a mixture to make it pumpable. This is called diluent
mineral oil.
|
-
.3 add the resultant multiples to obtain the value Sp
;
-
.4 refer to the left-hand column of the flow chart
for determining pollution categories and identify the row that corresponds
to the value of Sp
;
-
.5 read across this row, answering the relevant
questions in the middle column, to determine the pollution category
of the mixture, as shown in the right-hand column.
Flow chart for determining pollution categories
|
Sum of multiples (Sp)
|
Other factors (where relevant)
|
Pollution Category
|
Sp
≥ 10,000
|
Is the total percentage
of substances identified in Note 1 ≥ 1% wt?
|
Yes.................................................
|
A
|
No... Is
the sum of poll. cat. A multiples ≥ 10,000?
|
Yes......
|
A
|
|
No.......
|
B
|
10,000 >
Sp
≥ 1,000
|
Is the total percentage
of substances identified in Note 1 ≥ 1% wt?
|
Yes.................................................
|
A
|
No... Is
the sum of poll. cat. A & B multiples ≥ 1,000?
|
Yes......
|
B
|
|
No.......
|
C
|
1,000 >
Sp
≥100
|
|
Is the Sum
of poll. cat. A, B, & C
|
Yes......
|
C
|
|
multiples ≥
100?
|
No.......
|
D
|
100 >
Sp
≥ 10
|
..........................................................................................
|
D
|
10 >
Sp
|
..........................................................................................
|
App.
III
|
|
|
|
Note 1: Bioaccumulating and other highly toxic substances of
pollution Category A are only the following:
|
|
chlorinated paraffins (C10-C13)
|
|
diphenyl
|
|
diphenyl/diphenyl ether mixtures
|
|
dodecyl phenol
|
|
phosphorus, yellow or white
|
|
tricresyl phosphate, containing less than 1%
ortho-isomer
|
|
tricresyl phosphate, containing 1% or more
ortho-isomer
|
|
trixylyl phosphate.
|
5.4 Mixtures may contain aqueous solutions assessed
only within certain concentration limits. For the purpose of the calculation
in 5.3, the solution should be assumed to be at the highest assessed
concentration.
5.5 If the pollution category of the mixture is
either A or B or C, the next step is to calculate its ship type, by
the following procedure:
-
.1 identify the ship type of each component from
the IBC Code or the MEPC circular referred
to in 2.6;
-
.2 multiply the concentration of each component
in the mixture, expressed in per cent by weight, by the factor associated
to its ship type according to the following table 2;
Table 2
|
Ship type
|
Factor
|
1
|
100
|
2
|
10
|
3
|
1
|
Other
|
0
|
Diluent
mineral oil
|
|
in
lube oil additives
|
1
|
-
.3 add the resultant multiples to obtain the value Ss
;
-
.4 refer to the left-hand column of the flow chart
for determining ship types and identify the row that corresponds to
the value of Ss
;
-
.5 read across this row, answering the relevant
questions in the middle column, to determine the ship type for the
mixture, as shown in the right-hand column.
Flow chart for determining ship types
|
Sum of multiples (Ss)
|
Other Factors (where relevant)
|
|
Ship type
|
Ss
≥ 1,000
|
Is the sum of ship type
1 multiples ≥ 1,000?
|
Yes......
|
1
|
No.......
|
2
|
1,000 >
Ss
≥ 100
|
Is the sum of ship type
1 & 2 multiples ≥ 100?
|
Yes......
|
2
|
No.......
|
3
|
100 >
Ss
≥ 10
|
.........................................................................
|
3
|
10 > Ss
|
Is the pollution
category of the mixture A, B or C?
|
Yes......
|
3
|
No.......
|
Not
applicable
|
5.6 Examples of the calculation of the pollution
category and the ship type of mixtures are given in annex 9.
5.7 On the basis of the pollution category and
ship type so calculated and of its flashpoint, melting point and viscosity,
a mixture is then assigned to the appropriate “Noxious (or non-noxious)
liquid, n.o.s.” generic entry to the IBC Code with
the corresponding carriage requirements.
5.8 A Mixture is designated in the shipping document
by reference to the appropriate generic entry to the IBC
Code, completed by the indication of a trade name and of one
or two components most responsible for the assigned pollution category.
Trade names should not be such as to be confused with generally used
chemical descriptions. Components should be identified by their name
in either the IBC Code or the MEPC circular
referred to in 2.6.
5.9 With reference to 5.3.5, the diluent mineral
oil could be responsible for pollution category C being assigned to
a lube oil additive mixture. In this case, the designation of the
mixture should include the mention "contains mineral oil".
5.10 The process of assigning a pollutant-only
mixture of assessed components to one of the 18 generic entries to
the IBC Code is of a purely mechanical nature
and does not involve any assessment whatsoever. In the interest of
facilitating shipments, the Administration may authorize the manufacturer
to carry out the assignment on its behalf.
5.11 In this case, the obligation to inform the
flag States and the receiving countries of the performed assignment
falls on the delegated manufacturer. The manufacturer should also
inform IMO if so requested by the authorizing Administration. Notification
of the assignment by the manufacturer should be accompanied by the
authorization letter indicating that the manufacturer acts under instruction
and on behalf of the Administration until such authorization is recorded
in the MEPC circular referred to in 2.8 above.
5.12 The manufacturer should inform the authorizing
Administration of the assignment performed along with the details
of the assignment. Upon request, the manufacturer should also provide
the flag State and/or the receiving country with details of the mixture
assignment.